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Q1-3:Under certain conditions ethane will react slowly with bromine.

 
1. The conditions required for this reaction are ...
  • A.   a temperature of 300oC
  • B.   a catalyst of alumina or silica
  • C.   sunlight or u.v. light
  • D.   a pressure of 60atm
2. The correct equation for the reaction between ethane and bromine is ...
  • A.  C2H6 + Br2  C2H5Br + HBr
  • B.  C2H6 + Br2  C2H4Br2 + H2
  • C.  C2H6 + Br2  C2H6Br2 
  • D.  C2H4 + Br2  C2H4Br2  
 
3. The reaction between ethane and bromine is a(n) reaction.
4. Isomers are molecules with the ...
  • A.   same general formula but a different structural formula
  • B.   same molecular formula but a different structural formula
  • C.   same general formula but a different molecular formula
  • D.   same molecular formula but a different functional group

5. Hexane has the structure:       

hexane structure

Which one of the following is an isomer of hexane?

 

     4 x isomer structure

6. Which of the following structures, X, Y and Z are isomers of C4H8 ?

isomers XYZ

 
  • A.   X only
  • B.   X and Y only
  • C.   X and Z only
  • D.   X, Y and Z

Q7-10 refer to the following compounds, P, Q, R and S:

 

 

7. Which compounds are isomers?

  • A.   P and Q
  • B.   P and R
  • C.   R and S
  • D.   Q and S
8. Which compound(s) will decolourise bromine water immediately?
  • A.   P and Q
  • B.   P and R
  • C.   R and S
  • D.   Q and S
9. Which compound(s) can form addition polymers?
  • A.   P and Q
  • B.   P and R
  • C.   R and S
  • D.   Q and S

10. Which compounds are different members of the same homologous series?

  • A.   P and Q
  • B.   P and R
  • C.   R and S
  • D.   Q and S
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Question 1:

The correct answer is C. sunlight or u.v. light.

Explanation:
Ethane reacts with bromine via a free-radical substitution mechanism. This reaction requires energy to break the bromine-bromine bond homolytically to form bromine radicals. The most common way to initiate this is by providing ultraviolet (u.v.) light or sunlight.


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Question 2:

The correct answer is A. C₂H₆ + Br₂ → C₂H₅Br + HBr

Explanation:
The reaction between ethane and bromine under u.v. light is a substitution reaction. One hydrogen atom in the ethane molecule is replaced by a bromine atom, forming bromoethane (C₂H₅Br) and hydrogen bromide (HBr) as a byproduct.


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Question 3:

The correct answer is substitution (specifically, a free-radical substitution reaction).

Explanation:
In this reaction, a bromine atom replaces (substitutes) one of the hydrogen atoms on the ethane molecule. The original C-H bond is broken, and a new C-Br bond is formed, while the displaced hydrogen pairs with the other bromine atom to form HBr.

Because it involves alkanes (which are saturated hydrocarbons) and takes place via a chain mechanism involving bromine radicals, it is more precisely called a free-radical substitution reaction.


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 4:

The correct answer is B. same molecular formula but a different structural formula.

Explanation:
Isomers are compounds that have the same number and type of atoms (i.e., the same molecular formula) but are arranged differently in space or have different connectivity between those atoms (i.e., a different structural formula).


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 5:

Understanding Isomers

Isomers are molecules that have the same molecular formula (the same number of each type of atom) but a different structural arrangement.

Hexane's Formula: Hexane is an alkane with 6 carbon atoms and 14 hydrogen atoms

Option A has a double bond and only 12 hydrogen atom, so is not an isomer of hexane.

Option B and C are just Hexane:

If you trace the carbon line from the bottom-left branch, through the middle four carbons, and up to the top-right branch, it forms one single, continuous, unbranched chain of 6 carbons. C does the same thing in an L-shape. Because they are unbranched, B and C are just hexane drawn in a bent shape, not isomers.

Option D is a true Isomer:

It consists of a 4-carbon main chain (butane) with two methyl branches -CH3 attached to the middle carbons. This molecule is 2,3-dimethylbutane.Since it has the same molecular formula C6H14 but a completely different branched structure, D is the correct structural isomer.


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Question 6:

To determine which structures are isomers of C4H8 we must count the carbon (C) and hydrogen (H) atoms in each structure.

Isomers share the same molecular formula but have different arrangements.

Breakdown of Structures

Structure Formula Isomer of C4H8?
X (But-1-ene) C4H8 Yes
Y (Butane) C4H10 No
Z (Cyclobutane) C4H8 Yes

Conclusion

Both X and Z have the molecular formula C4H8. Therefore, the correct answer is C (X and Z only).


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Question 7:

First, let's identify the molecular formula for each compound:

P: C4H10 (Butane)

Q: C4H8 (But-1-ene)

R: C3H8 (Propane)

S: C4H8 (But-2-ene)

Which compounds are isomers?

Isomers are molecules that have the same molecular formula but different structural arrangements.Q and S both have the formula C4H8.

Answer: D. Q and S


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Question 8:

First, let's identify the molecular formula for each compound:

P: C4H10 (Butane)

Q: C4H8 (But-1-ene)

R: C3H8 (Propane)

S: C4H8 (But-2-ene)

Which compound(s) will decolourise bromine water immediately?

Bromine water is a test for unsaturation (double or triple bonds). Compounds with C=C double bonds (alkenes) react quickly with bromine water, changing it from orange/brown to colorless.

Q and S are both alkenes containing a double bond.

Answer: D. Q and S


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Question 9:

First, let's identify the molecular formula for each compound:

P: C4H10 (Butane)

Q: C4H8 (But-1-ene)

R: C3H8 (Propane)

S: C4H8 (But-2-ene)

Addition polymerization requires unsaturated monomers that contain at least one carbon-carbon double bond C=C.

Q and S are alkenes containing double bonds, which can open up to link together into long polymer chains.

Correct Answer: D (Q and S)


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Question 10:

First, let's identify the molecular formula for each compound:

P: C4H10 (Butane)

Q: C4H8 (But-1-ene)

R: C3H8 (Propane)

S: C4H8 (But-2-ene)

A homologous series is a family of organic compounds that share the same general formula, functional group, and similar chemical properties, with each consecutive member differing by a -CH2 unit.

P (Butane), C4H10 and R (Propane, C3H8) are both alkanes sharing the general formula CnH2n+2.

Correct Answer: B (P and R)


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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