10 minutes maximum!
1. Select the row showing the correct flame colours for the following ions:
3. Chloride, bromide, and iodide ions in solution can be tested for by adding ...
4. A student was given an unknown solid, P, to identify. She dissolved a small sample of the solid in water and tested as follows:
She correctly concluded that solid P was ...
This yellow precipitate is ...
The observation she made and the name of the substance responsible for this observation is ...
7. Identify the white solid which gave the following results when tested:
8. A solution was tested as follows to identify the negative ion present:
The negative ion present could be ...
9-10. A teacher suspected that a sodium sulfate solution had been contaminated. She tested the solution and obtained the following results:
10. Identify the negative ion contaminating the sodium sulfate solution.
Question 1:
Let's recall the standard flame test colors:
Li⁺ → red / crimson
Na⁺ → yellow / orange-yellow (often just "yellow")
K⁺ → lilac
Cu²⁺ → blue-green (or green)
This matches row D
*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret. Grade Gorilla uses Gemini, Deepseek and a range of other A.I. chatbots to generate the saved responses. Some answers have had human intervention for clarity or where the A.I. has not been able to answer the question.
Question 2:
Let's break down the observations:
Fizzes with acid → gas produced
Gas turns limewater milky → this is the test for carbon dioxide (CO₂)
So the gas is CO₂.
CO₂ is produced when a carbonate (CO₃²⁻) reacts with an acid:
CO₃²⁻ + 2H+ → CO₂ + H₂O
Therefore, the ion present in Z is carbonate.
Options: A. sulphate ❌ (no fizzing with acid under normal conditions, and gas not CO₂) B. nitrate ❌ (no fizzing with acid like carbonate; CO₂ not produced) C. carbonate ✅ D. carbon dioxide ❌ (this is a gas, not an ion in the solid/liquid before reaction)
Answer: C ✅
Question 3:
Let's recall the standard test for halide ions (chloride, bromide, iodide) in solution:
Add dilute nitric acid — to remove any carbonate ions that might give a false precipitate with silver nitrate.
Add silver nitrate solution — forms precipitates:
AgCl → white
AgBr → cream
AgI → yellow
So the correct sequence is: dilute nitric acid followed by silver nitrate solution.
Now check the options:
A. dilute nitric acid followed by silver nitrate solution ✅ B. dilute nitric acid followed by barium chloride solution ❌ (barium chloride tests for sulfates) C. dilute hydrochloric acid followed by silver nitrate solution ❌ (hydrochloric acid adds chloride ions, giving a false positive for chloride) D. dilute hydrochloric acid followed by barium chloride solution ❌ (wrong order & wrong chemicals for halides)
Answer: A ✅
Question 4:
1. Adding sodium hydroxide solution → brown precipitate forms
Brown precipitate with NaOH indicates iron(III) ions (Fe³⁺). Iron(II) (Fe²⁺) would give a green precipitate (which turns brown on standing in air, but the immediate result here is described as brown, so Fe³⁺ is more likely if it’s described as immediately brown). → So cation is likely Fe³⁺ (iron(III)). → Options A and B (iron(II)) are less likely.
2. Add hydrochloric acid then barium chloride solution → white precipitate forms
Barium chloride solution (BaCl₂) is used to test for sulfate ions (SO₄²⁻).
A white precipitate (BaSO₄) forms when sulfates are present.
The hydrochloric acid is added first to remove any carbonates or other ions that might interfere.
White precipitate = sulfate present.
3. Combining both conclusions
Cation: Fe³⁺ (from step 1)
Anion: SO₄²⁻ (from step 2)
So the compound is iron(III) sulfate.
Answer: D ✅
Question 5:
Let’s think this through.
A yellow precipitate with silver nitrate solution indicates the presence of a halide ion.
Silver chloride (AgCl) is white
Silver bromide (AgBr) is cream (off-white/pale yellow — sometimes described as pale yellow, but in contrast, iodide is distinctly yellow)
Silver iodide (AgI) is yellow
In most exam contexts:
AgCl → white (soluble in dilute ammonia)
AgBr → cream (slightly soluble in concentrated ammonia)
AgI → yellow (insoluble in ammonia)
So the yellow precipitate is silver iodide, which means the original substance contained iodide ions (I⁻).
Check the options:
A. silver bromide → cream, not yellow ❌ B. silver iodide → yellow ✅ C. barium nitrate → wouldn’t form a precipitate with silver nitrate under normal circumstances ❌ D. lead(II)nitrate → not relevant (Pb²⁺ would give a precipitate with some anions, but the description says “yellow precipitate when added to silver nitrate” — it’s AgI) ❌
Answer: B ✅
Question 6:
1. Understanding the test The student made lithium sulfate solution. She then added acidified barium chloride solution (BaCl₂ in HCl).
The purpose of acidified barium chloride is to test for sulfate ions (SO₄²⁻). When Ba²⁺ from BaCl₂ meets SO₄²⁻ in solution in acidic conditions, it forms barium sulfate (BaSO₄), which is a white precipitate (insoluble in acid).
2. What happens here? Lithium sulfate → contains SO₄²⁻ ions. So: Ba²⁺(aq) + SO₄²⁻(aq) → BaSO₄(s) (white precipitate)
3. Matching with options
Observation: White precipitate Substance responsible (for the precipitate): Barium sulfate (not lithium chloride — LiCl is soluble, not a precipitate here)
That matches option A.
A: White precipitate – Barium sulfate ✅
B: White precipitate – Lithium chloride ❌ (wrong substance)
C: Cream precipitate ❌ (wrong color, wrong substance)
D: Cream precipitate ❌ (wrong color, wrong substance)
Question 7:
Let’s analyze each test result.
1. Flame test → Lilac flame Lilac flame indicates potassium (K⁺). → So the compound contains K⁺, not Li⁺. That rules out A (lithium carbonate) and C (lithium sulfate).
Remaining: B (potassium carbonate) and D (potassium sulfate).
2. Add HCl then BaCl₂ → Bubbles produced, no precipitate
Bubbles = gas formed → suggests a carbonate (CO₃²⁻), because CO₃²⁻ + 2H⁺ → CO₂ + H₂O (bubbles)
No precipitate with BaCl₂ after adding HCl means no sulfate (BaSO₄ would be a white precipitate).
So: carbonate present ✅, sulfate absent ❌
3. Match with options
B. potassium carbonate → K⁺ (lilac flame) ✅, CO₃²⁻ (bubbles with acid) ✅, no sulfate (no precipitate with BaCl₂) ✅
D. potassium sulfate → K⁺ (lilac flame) ✅, but bubbles? ❌ (sulfate doesn’t produce bubbles with acid), plus would give white precipitate with BaCl₂ ❌
Question 8:
Let’s interpret the test results step-by-step.
1. Add dilute hydrochloric acid → No effervescence
Effervescence would mean gas given off, most likely CO₂ from carbonate (CO₃²⁻ + 2H⁺ → CO₂ + H₂O).
No effervescence means carbonate absent. → Rules out B. carbonate ion.
2. Add acidified silver nitrate → No precipitate formed
Acidified AgNO₃ tests for halide ions (Cl⁻, Br⁻, I⁻).
White precipitate = Cl⁻, cream = Br⁻, yellow = I⁻.
No precipitate means no halide ions present. → Rules out D. bromide ion.
3. Add acidified barium chloride → No precipitate formed
Acidified BaCl₂ tests for sulfate ions (SO₄²⁻ → white precipitate BaSO₄).
No precipitate means sulfate absent. → Rules out A. sulfate ion.
4. Remaining possibility
The only left from the options is nitrate ion (NO₃⁻). Nitrate would give:
No effervescence with acid (unless reducing agent present, but not here)
No precipitate with Ag⁺ or Ba²⁺ under these conditions
✅ So the negative ion could be nitrate.
Question 9:
Let's reason through the results.
1. Sodium sulfate solution → main compound = Na₂SO₄ (sodium ions + sulfate ions) Contamination means: some other positive (cation) or negative (anion) ion is present.
2. Flame test → Yellow flame
Yellow flame = sodium ions (Na⁺)
This is already expected from the sodium sulfate, so this result doesn’t indicate a contaminant — just confirms Na⁺ is present.
3. Add sodium hydroxide solution → Green precipitate formed
Transition metal hydroxides:
Cu²⁺ → blue precipitate
Fe²⁺ (iron(II)) → green precipitate
Fe³⁺ (iron(III)) → red-brown precipitate
So green precipitate = Fe²⁺ (iron(II) ions). → This suggests the positive ion contaminant is iron(II).
4. Add acidified silver nitrate → White precipitate formed
White precipitate with AgNO₃ = chloride ions (Cl⁻), but question asks for positive ion contaminant, so this confirms maybe chloride is present, not relevant to positive ion identification.
5. Add acidified barium chloride → White precipitate formed
White precipitate = sulfate ions (already present from sodium sulfate), confirms SO₄²⁻ is there, not a contaminant.
6. Which positive ion contaminant?
Given Fe²⁺ gives a green precipitate with NaOH and fits all, the positive ion contaminating is iron(II) ion.
→ option C.
Question 10:
Let’s look at the test results again, focusing on the negative ion contaminant.
Given in the earlier table:
Add acidified silver nitrate solution → White precipitate formed White precipitate with acidified AgNO₃ = chloride ions (Cl⁻) (AgCl is white).
Bromide gives cream, iodide gives yellow — not white. Sulfate does not give a precipitate with AgNO₃ under normal conditions (Ag₂SO₄ is slightly soluble but not a white precipitate in this context; and the solution is acidified to prevent carbonate interference, not to precipitate sulfate).
But the original solution is sodium sulfate — so sulfate is already present, not a contaminant.
So the white precipitate with acidified AgNO₃ means a chloride contaminant is present (Cl⁻).