An IB Chemistry data booklet is helpful
1. What is the empirical formula of a compound containing 79.9% by mass of carbon and 20.1% by mass of hydrogen?
3. A sample of an oxide of sulfur was analysed and found to contain 1.6g of sulfur and 2.4g of oxygen. What is its empirical formula?
6. Which of the following compounds has/have the empirical formula CH2O?
Question 1:
To determine the empirical formula of a compound containing 79.9% carbon and 20.1% hydrogen by mass, follow these steps:
Assume a 100 g sample:
Mass of carbon = 79.9 g
Mass of hydrogen = 20.1 g
Convert masses to moles:
Moles of carbon = 79.9/12.01≈6.6536 mol
Moles of hydrogen = 20.1/1.008≈19.9405 mol
Find the simplest mole ratio:
Divide each by the smallest number of moles (which is carbon, 6.6536):
Carbon: 6.6536 / 6.6536=1
Hydrogen: 19.9405 / 6.6536≈2.996≈3
Write the empirical formula:
The ratio is C : H = 1 : 3, so the empirical formula is CH₃.
Answer: B. CH₃
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Question 2:
Assume a 100 g sample of the oxide:
Mass of oxygen = 32 g
Mass of metal X = 100 g - 32 g = 68 g
Now, convert masses to moles:
Moles of X = mass / atomic mass = 68 g / 51 g/mol ≈ 1.3333 mol
Moles of O = 32 g / 16 g/mol = 2.000 mol
Find the simplest mole ratio by dividing both by the smaller number of moles (which is 1.3333):
For X: 1.3333 / 1.3333 = 1
For O: 2.000 / 1.3333 ≈ 1.5
To get whole numbers, multiply both by 2:
X: 1 × 2 = 2
O: 1.5 × 2 = 3
Thus, the empirical formula is X₂O₃.
Answer: D. X₂O₃
Question 3:
To determine the empirical formula of the oxide of sulfur given:
Mass of sulfur = 1.6 g
Mass of oxygen = 2.4 g
Follow these steps:
Molar mass of sulfur (S) = 32 g/mol
Molar mass of oxygen (O) = 16 g/mol
Moles of S = 1.6/32=0.05 mol
Moles of O = 2.4/16=0.15 mol
Divide both by the smallest number of moles (which is 0.05):
S: 0.05/0.05=1
O: 0.15/0.05=3
The ratio is S : O = 1 : 3, so the empirical formula is SO₃.
Answer: B. SO₃
Question 4:
To find the molecular formula of melamine given:
Empirical formula = CH₂N₂
Molecular mass = 126 g/mol
Calculate the empirical formula mass:
Carbon (C): 12 g/mol × 1 = 12 g/mol
Hydrogen (H): 1 g/mol × 2 = 2 g/mol
Nitrogen (N): 14 g/mol × 2 = 28 g/mol
Total empirical mass = 12 + 2 + 28 = 42 g/mol
Determine the multiple (n):
n = Molecular mass / Empirical mass = 126 / 42 = 3
Multiply the empirical formula by n:
Molecular formula = (CH₂N₂) × 3 = C₃H₆N₆
Answer: C. C₃H₆N₆
Question 5:
To determine the empirical formula of the oxide of chromium:
Given:
Mass of the oxide = 5.0 g
Mass of chromium in the oxide = 2.6 g
First, find the mass of oxygen:
Mass of oxygen = Total mass of oxide - Mass of chromium = 5.0 g - 2.6 g = 2.4 g
Molar mass of chromium (Cr) = 52 g/mol
Moles of Cr = 2.6/52=0.05 mol
Find the simplest mole ratio by dividing both by the smallest number of moles (0.05):
Cr: 0.05/0.05=1
The ratio is Cr : O = 1 : 3, so the empirical formula is CrO₃.
Answer: B. CrO₃
Question 6:
To determine which compounds have the empirical formula CH₂O, we need to simplify each molecular formula to its simplest whole-number ratio.
Recall: The empirical formula CH₂O has a ratio of C : H : O = 1 : 2 : 1.
Let's analyze each compound:
I. C₆H₁₂O₆
Divide all subscripts by 6: C₆/₆ H₁₂/₆ O₆/₆ = CH₂O
So, it has the empirical formula CH₂O.
II. CH₃COOH (which is C₂H₄O₂)
Divide all subscripts by 2: C₂/₂ H₄/₂ O₂/₂ = CH₂O
III. C₁₂H₂₄O₁₁
The ratio is C : H : O = 12 : 24 : 11.
This cannot be simplified to a 1:2:1 ratio because 11 (for oxygen) is not divisible to give 1. The closest would be C₁₂H₂₄O₁₁, which is not CH₂O (since CH₂O requires O=1, but here O=11/12? Not integer).
Actually, divide by 12: C₁₂/₁₂ H₂₄/₁₂ O₁₁/₁₂ = C₁ H₂ O₀.9167... which is not a whole number. So, it does not simplify to CH₂O.
Therefore, only I and II have the empirical formula CH₂O.
Answer: B. I and II only
Question 7:
To determine the molecular formula of the hydrocarbon, let's analyze the combustion reaction:
The hydrocarbon (CxHy) burns in oxygen to produce CO₂ and H₂O:
0.25 mol of hydrocarbon produces:
44.0 g of CO₂
22.53 g of H₂O
Step 1: Find the moles of CO₂ and H₂O produced
Molar mass of CO₂ = 44 g/mol
Moles of CO₂ = 44.0/44=1.0 mol
Molar mass of H₂O = 18 g/mol
Moles of H₂O = 22.53/18≈1.2517 mol
Step 2: Relate these to the moles of hydrocarbon Since 0.25 mol of hydrocarbon produces:
1.0 mol of CO₂ ⇒ This means x=(moles of CO₂) / (moles of hydrocarbon) x =1.0/0.25=4
1.2517 mol of H₂O ⇒ This means (y/2)=(moles of H₂O) / (moles of hydrocarbon) (y/2)=1.2517/0.25=5.0068≈5 So, y=10
Step 3: Determine the molecular formula The hydrocarbon has the formula C₄H₁₀.
Answer: C. C₄H₁₀
Question 8:
To determine the number of moles of water of crystallization (n n) in hydrated calcium sulfate (CaSO₄.nH₂O), follow these steps:
Mass of anhydrous CaSO₄ after heating = 2.72 g
Molar mass of CaSO₄ = 136 g/mol
Mass of hydrated salt before heating = 3.44 g
Step 1: Calculate the mass of water lost:
Step 2: Calculate moles of anhydrous CaSO₄:
Step 3: Calculate moles of water lost:
Step 4: Find the ratio of moles of water to moles of CaSO₄ :
Thus, the formula of the hydrated salt is CaSO₄.H₂O
Answer: B. 2
Question 9:
To determine the empirical formula of the hydrocarbon from its combustion products:
Mass of CO₂ produced = 4.40 g
Mass of H₂O produced = 2.70 g
Step 1: Find the moles of carbon and hydrogen in the hydrocarbon
All carbon in the hydrocarbon ends up in CO₂.
Moles of CO₂ = 4.40/44=0.10 mol
Each mole of CO₂ contains 1 mole of C, so moles of C = 0.10 mol
All hydrogen in the hydrocarbon ends up in H₂O.
Moles of H₂O = 2.70/18=0.15 mol
Each mole of H₂O contains 2 moles of H, so moles of H = 0.15 × 2 = 0.30 mol
Step 2: Find the simplest mole ratio (C : H)
Divide both by the smallest number (0.10):
C: 0.10/0.10=1
H: 0.30/0.10=3
So, the empirical formula is CH₃.
Answer: C. CH₃
Question 10:
To determine which compound has the highest percentage by mass of nitrogen, we'll calculate the mass percentage of nitrogen in each option.
A. NH₃ (Ammonia)
Molar mass = 14 + 3(1) = 17 g/mol
Mass of N = 14 g
% N = 14/17×100%≈82.35%
B. NH₄NO₃ (Ammonium nitrate)
Molar mass = 14 + 4(1) + 14 + 3(16) = 18 + 14 + 48 = 80 g/mol
Mass of N = 14 + 14 = 28 g (two N atoms)
% N = 28/80×100%=35.00%
C. CO(NH₂)₂ (Urea)
Molar mass = 12 + 16 + 2(14) + 4(1) = 12 + 16 + 28 + 4 = 60 g/mol
Mass of N = 28 g (two N atoms)
% N = 28/60×100%≈46.67%
D. (NH₄)₂SO₄ (Ammonium sulfate)
Molar mass = 2(14) + 8(1) + 32 + 4(16) = 28 + 8 + 32 + 64 = 132 g/mol
% N = 28/132×100%≈21.21%
Comparing the percentages:
A. NH₃: ~82.35%
B. NH₄NO₃: 35.00%
C. Urea: ~46.67%
D. (NH₄)₂SO₄: ~21.21%
NH₃ has the highest percentage by mass of nitrogen.
Answer: A. NH₃